The super duplex tier of stainless steel is defined by a single chemistry threshold: pitting resistance equivalent number (PREN) ≥ 40, calculated as Cr + 3.3 × Mo + 16 × N. Grades that fall below 40 are standard duplex (the dominant 22Cr grades S31803 / S32205, PREN ~35), grades at or above 40 are super duplex. Five grades hold most of the commercial market by tonnage, distinguished by their alloying-element strategy. The Cu-bearing grade Ferralium 255 (UNS S32550) carries 2 percent copper for reducing-acid service. The 2507 family (UNS S32750) is the most-stocked grade with the widest standards coverage. The W-bearing Zeron 100 (UNS S32760) carries 0.7 percent tungsten that contributes a half-point of PREN equivalence and improves crevice resistance. Two newer grades round out the modern super duplex lineup with slightly different alloying strategies for specific service envelopes.
PREW (PREN with W) = Cr + 3.3 × (Mo + 0.5 × W) + 16 × N. The W contribution recognises the synergistic effect of tungsten on crevice corrosion resistance.
- Default for sour service + chloride combination: 2507 (S32750), broadest standards coverage, easiest to procure, highest PREN at 43
- For reducing-acid service (H2SO4, HCl, phosphoric): Ferralium 255 (S32550), the 2% Cu addition is the differentiator
- For severe crevice / cathodic-protection-coupled service: Zeron 100 (S32760), W contribution gives crevice-resistance margin
- For high-strength forging where N is the strengthening route: SAF 2906 (S32906), 0.40% N, lean Mo
- For mid-cost commercial bolting in moderate sour: Ferralium 255, typically 15 to 25% lower stocked cost than 2507
- Passivation (ASTM A967)
- Pickling (ASTM A380)
- Electropolishing
- Mill / 2B / 2D / BA finish
- Bright bar / centreless ground
- Peeled & polished bar
- Shot-blast (EN 10088-2)